منابع مشابه
Formation and distribution of neutral vanadium, niobium, and tantalum oxide clusters: single photon ionization at 26.5 eV.
Neutral vanadium, niobium, and tantalum oxide clusters are studied by single photon ionization employing a 26.5 eV/photon soft x-ray laser. During the ionization process the metal oxide clusters are almost free of fragmentation. The most stable neutral clusters of vanadium, niobium, and tantalum oxides are of the general form (MO2)0,1(M2O5)y. M2O5 is identified as a basic building unit for thes...
متن کاملExploring the reactivity of framework vanadium, niobium, and tantalum sites in zeolitic materials using DFT reactivity descriptors
The acid-base properties of zeolites with group 5 transition metal framework sites are investigated, and a first step into the understanding of their acid/base and redox properties is undertaken using DFT reactivity descriptors. It is evidenced, using sodalite as model system, that zeolites with vanadium framework sites are more nucleophilic than zeolites with niobium and tantalum framework sit...
متن کاملNew synthesis of nanosized niobium oxides and lithium niobate particles and their characterization by XPS analysis.
This work presents a new synthesis of nano-sized lithium niobate particles by a low temperature three steps procedure. The complete protocol implies a LiH induced reduction of NbCl5 followed by in situ spontaneous oxidation into low valence niobium nano-oxides. These niobium oxides are exposed to air atmosphere leading to pure Nb2O5 formation. Finally, the stable Nb2O5 is converted into lithium...
متن کاملMetal effects on ligand non-innocence in Group 5 complexes of the redox-active [ONO] pincer ligand.
Isostructural vanadium, niobium and tantalum complexes of bis(3,5-di-tert-butyl-2-phenol)amine ([ONO]H3), were prepared and characterized to evaluate the impact of the metal ion on redox-activity of the ligand platform. New vanadium and niobium complexes with the general formula, [ONO]MCl2L (M = V, L = THF, 1-V; M = Nb, L = Et2O, 1-Nb) were prepared and structurally analysed by X-ray crystallog...
متن کاملGreen extraction of Niobium and Tantalum from Kenticha Tantalite ore using 1-Ethyl-3-Methyl Imidazolium Chloride ionic liquid
The decomposition of the Ethiopian Kenticha tantalite ore was studied using the KOH fusion and H2O leaching system at 400 0C for a 1 h reaction time. The experimental results obtained showed that 27 wt% of Ta2O5 was mainly transformed into insoluble KTaO3, not to be KNbO3, and as well, into the dissolved liquor containing 94.73 vol% of Nb2O5 and 75.80 vol% of Ta2O5. The observations, supported ...
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ژورنال
عنوان ژورنال: Surface Science Spectra
سال: 2017
ISSN: 1055-5269,1520-8575
DOI: 10.1116/1.4998018